The Amazing Spiderman #276. The Face Behind the Mask.  May 1986.  Titled "Unmasked!" Written by Tom DeFalco.

Hobgoblin believes he has defeated Spider-Man but he plays and dodges.  Spider-Man just wants the battle to end so he can end his career as a hero.  Spider-Man strikes him in the face with a web and Hobgoblin is forced to remove his mask.  The Hobgoblin flees not to expose himself.  Used.

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